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Diastereoselective formation of a complex with an atropisomeric 4,4′-biquinazoline ligand: The solid-state structure of cis-bis(4,4′-biquinazoline)dichloridoiridium(III) hexafluoridophosphate

Ademi, Lumni and Constable, Edwin C. and Housecroft, Catherine E. and Neuburger, Markus and Schaffner, Silvia. (2008) Diastereoselective formation of a complex with an atropisomeric 4,4′-biquinazoline ligand: The solid-state structure of cis-bis(4,4′-biquinazoline)dichloridoiridium(III) hexafluoridophosphate. Inorganic Chemistry Communications, 11 (5). pp. 564-567.

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Official URL: http://edoc.unibas.ch/dok/A6056004

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Abstract

The ligand 4,4`-biquinazoline (biqz) forms complexes in which it adopts either the P or M atropisomeric configuration; the complex cis-[1r(biqz)(2)Cl-2][PF6] center dot MeCN has been structurally characterised and shown to comprise a single enantionteric pair (PM-Delta)(MP-Lambda) of the six possible stereoisomers.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles and Housecroft, Catherine Elizabeth and Neuburger, Markus
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Elsevier
ISSN:1387-7003
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:10 Apr 2017 14:50
Deposited On:01 Feb 2013 08:40

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