Ademi, Lumni and Constable, Edwin C. and Housecroft, Catherine E. and Neuburger, Markus and Schaffner, Silvia. (2008) Diastereoselective formation of a complex with an atropisomeric 4,4′-biquinazoline ligand: The solid-state structure of cis-bis(4,4′-biquinazoline)dichloridoiridium(III) hexafluoridophosphate. Inorganic Chemistry Communications, 11 (5). pp. 564-567.
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Official URL: http://edoc.unibas.ch/dok/A6056004
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Abstract
The ligand 4,4`-biquinazoline (biqz) forms complexes in which it adopts either the P or M atropisomeric configuration; the complex cis-[1r(biqz)(2)Cl-2][PF6] center dot MeCN has been structurally characterised and shown to comprise a single enantionteric pair (PM-Delta)(MP-Lambda) of the six possible stereoisomers.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Constable) 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Housecroft) |
|---|---|
| UniBasel Contributors: | Constable, Edwin Charles and Housecroft, Catherine Elizabeth and Neuburger, Markus |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Elsevier |
| ISSN: | 1387-7003 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: | |
| Last Modified: | 10 Apr 2017 14:50 |
| Deposited On: | 01 Feb 2013 08:40 |
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