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Expanding the 4,4'-bipyridine ligand: Structural variation in {M(pytpy)2}2+ complexes (pytpy = 4'-(4-pyridyl)-2,2':6',2''-terpyridine, M = Fe, Ni, Ru) and assembly of the hydrogen-bonded, one-dimensional polymer {[Ru(pytpy)(Hpytpy)]}n3n+

Beves, Jonathon E. and Bray, David J. and Clegg, Jack K. and Constable, Edwin C. and Housecroft, Catherine E. and Jolliffe, Katrina A. and Kepert, Cameron J. and Lindoy, Leonard F. and Neuburger, Markus and Price, David J. and Schaffner, Silvia and Schaper, Frank. (2008) Expanding the 4,4'-bipyridine ligand: Structural variation in {M(pytpy)2}2+ complexes (pytpy = 4'-(4-pyridyl)-2,2':6',2''-terpyridine, M = Fe, Ni, Ru) and assembly of the hydrogen-bonded, one-dimensional polymer {[Ru(pytpy)(Hpytpy)]}n3n+. Inorganica Chimica Acta, 361 (9-10). pp. 2582-2590.

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Official URL: http://edoc.unibas.ch/dok/A6056003

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Abstract

The solid state structures of [Ni(1)(2)][NO3](2) center dot 2MeOH center dot 2H(2)O, [Fe(1)(2)][ClO4](2) center dot 2MeOH center dot 0.5H(2)O, [Ru(1)(2)][PF6](2) and [Ru(1)(2)][PF6] [NO3] (1 = 4 `-(4-pyridyl)-2,2 `:6 `,2 ``-terpyridine) are presented and the structural variation observed for the M(1)(2)(2+) unit is discussed. Protonation of the pendant pyridine group in [Ru(1)(2)](2+) leads to the formation of a hydrogen-bonded, one-dimensional polymer [Ru(1)(H1)(n)](3n+) exemplifed by the solid-state structure of [Ru(1)(H1)Fe(NCS)(6) center dot 1.25H(2)O](n).
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles and Housecroft, Catherine Elizabeth
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Elsevier
ISSN:0020-1693
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:10 Apr 2017 14:53
Deposited On:01 Feb 2013 08:40

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