edoc

Homoleptic metal complexes of 4'-(5-pyrimidinyl)-2,2':6',2''-terpyridine : tetrafurcated expanded ligands

Beves, Jonathon E. and Constable, Edwin C. and Decurtins, Silvio and Dunphy, Emma L. and Housecroft, Catherine E. and Keene, Tony D. and Neuburger, Markus and Schaffner, Silvia. (2008) Homoleptic metal complexes of 4'-(5-pyrimidinyl)-2,2':6',2''-terpyridine : tetrafurcated expanded ligands. CrystEngComm, 10 (8). pp. 986-990.

Full text not available from this repository.

Official URL: http://edoc.unibas.ch/dok/A6055998

Downloads: Statistics Overview

Abstract

With iron(II) and ruthenium(II), 4`-(5-pyrimidinyl)-2,2`: 6`,2 ``-terpyridine (L) preferentially coordinates through the tpy domain to give octahedral [ML2](2+) (M Fe, Ru) complexes. Treatment of [RuL2][PF6](2) with CuCl2 center dot 2H(2)O leads to [Ru(2)(2)][CuCl2(OH2)][CuCl3]Cl center dot 3MeCN center dot 7H(2)O(n) which exhibits a two-dimensional coordination network with copper(II) centres interconnecting [RuL2](2+) motifs. Magnetic susceptibility data for the material are consistent with a one-dimensional S = 1/2 antiferromagnetic chain.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles and Housecroft, Catherine Elizabeth and Neuburger, Markus
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Royal Society of Chemistry
e-ISSN:1466-8033
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:12 Apr 2017 06:34
Deposited On:01 Feb 2013 08:40

Repository Staff Only: item control page