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Nanoscale octadecacobalta- and hexacosacobaltaclusters : synthesis and spectroscopic fingerprinting

Constable, Edwin C. and Gusmeroli, Deborah and Housecroft, Catherine E. and Neuburger, Markus and Schaffner, Silvia. (2007) Nanoscale octadecacobalta- and hexacosacobaltaclusters : synthesis and spectroscopic fingerprinting. Polyhedron, 26 (6). pp. 1222-1228.

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Official URL: http://edoc.unibas.ch/dok/A6056013

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Abstract

Strategies for the construction of TMS-protected first generation star and dendritic polyynes, which are subsequently metallated to give multiple CO2C2(CO)(6) clusters, are reported. In the absence of crystallographic data, well-resolved C-13 NMR spectroscopy is a powerful technique for confirming the presence of core, inner and peripheral cluster domains.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles and Housecroft, Catherine Elizabeth
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Elsevier
ISSN:0277-5387
e-ISSN:1873-3719
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:12 Apr 2017 07:26
Deposited On:01 Feb 2013 08:39

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