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Amphiphilic PEG-b-PMCL-b-PDMAEMA Triblock Copolymers : from Synthesis to Physico-Chemistry of Self-Assembled Structures

Matter, Y. and Enea, R. and Casse, O. and Lee, C. C. and Baryza, J. and Meier, W.. (2011) Amphiphilic PEG-b-PMCL-b-PDMAEMA Triblock Copolymers : from Synthesis to Physico-Chemistry of Self-Assembled Structures. Macromolecular Chemistry and Physics, 212 (9). pp. 937-949.

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Official URL: http://edoc.unibas.ch/dok/A6001620

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Abstract

A synthetic route toward a new family of amphiphilic mPEG-b-PMCL-b-PDMAEMA triblock copolymers is reported. Chemical structures and compositions are confirmed by (1)H NMR and SEC. Polydispersity indices are typically >1.4, indicating good control of the reactions. The physicochemical parameters associated with mPEG-b-PMCL-b-PDMAEMA self-assembled structures are investigated. Nanoparticles are prepared via a co-solvent method, and parameters such as nanoparticle >(M)over bar<(w), N(agg), A(2), and R(h) are calculated based on static and dynamic light scattering data. Critical aggregation concentrations for the polymers are determined by measuring surface tensions of polymer solutions. TEM is employed to visualize the morphology of the assemblies.
Faculties and Departments:05 Faculty of Science > Departement Chemie
05 Faculty of Science > Departement Chemie > Chemie > Makromolekulare Chemie (Meier)
UniBasel Contributors:Meier, Wolfgang P.
Item Type:Article, refereed
Article Subtype:Research Article
Bibsysno:Link to catalogue
Publisher:Wiley
ISSN:1022-1352
e-ISSN:1521-3935
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:04 Jun 2018 12:50
Deposited On:08 Nov 2012 16:10

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