Nagy, Adam and Fulara, Jan and Garkusha, Iryna and Maier, John P.. (2011) On the Benzylium/Tropylium Ion Dichotomy: Electronic Absorption Spectra in Neon Matrices. Angewandte Chemie International Edition, 50 (13). pp. 3022-3025.
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Abstract
Benzyl and tropyl in charge: Electronic spectra of mass-selected benzylium (Bz+) and tropylium (Tr+) cations embedded in solid neon are reported for the first time. They reveal a weak (1)1B1←equation image1A1 visible (see picture) and a much stronger (1)1A1←equation image1A1 ultraviolet transition for Bz+ (C2v symmetry). The lowest dipole-allowed 1A′′2←equation image1A′1 absorption in the ultraviolet region for Tr+ (D7h) is also observed.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Physikalische Chemie (Maier) |
|---|---|
| UniBasel Contributors: | Nagy, Adam and Fulara, Jan and Roth, Iryna and Maier, John Paul |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Wiley |
| ISSN: | 1433-7851 |
| e-ISSN: | 1521-3773 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Language: | English |
| Identification Number: | |
| edoc DOI: | |
| Last Modified: | 16 Feb 2017 09:33 |
| Deposited On: | 14 Sep 2012 07:15 |
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