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A Synthetic Entry into the Taiwaniaquinoids Based on a Biogenetic Hypothesis : Total Synthesis of (-)-Taiwaniaquinone H

Jana, C. K. and Scopelliti, R. and Gademann, K.. (2010) A Synthetic Entry into the Taiwaniaquinoids Based on a Biogenetic Hypothesis : Total Synthesis of (-)-Taiwaniaquinone H. Chemistry - A European Journal, 16 (26). pp. 7692-7695.

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Official URL: http://edoc.unibas.ch/dok/A5841598

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Abstract

Less carbon: Following a biogenetic proposal, the unusual 6-5-6 carbon skeleton of C19 taiwaniaquinoids was obtained by an intramolecular benzilic acid rearrangement from a C20 precursor. A protecting-group-free total synthesis then allowed for the preparation of (−)-taiwaniaquinone H (see scheme).
Faculties and Departments:05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Organische Chemie (Gademann)
UniBasel Contributors:Gademann, Karl
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Wiley
ISSN:0947-6539
e-ISSN:1521-3765
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
Identification Number:
Last Modified:04 Oct 2017 08:43
Deposited On:14 Sep 2012 06:55

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