X-ray structure and designed evolution of an artificial transfer hydrogenase

Creus, Marc and Pordea, Anca and Rossel, Thibaud and Sardo, Alessia and Letondor, Christophe and Ivanova, Anita and LeTrong, Isolde and Stenkamp, Ronald E. and Ward, Thomas R.. (2008) X-ray structure and designed evolution of an artificial transfer hydrogenase. Angewandte Chemie International Edition, 47 (8). pp. 1400-1404.

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Official URL: http://edoc.unibas.ch/dok/A5254441

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A structure is worth a thousand words: guided by the crystal structure of an S-selective artificial transfer hydrogenase, designed evolution was used to optimize the selectivity of hybrid catalysts. Fine-tuning of the second coordination sphere of the ruthenium center by introduction of two point mutations allowed the identification of selective artificial transfer hydrogenases for the redn. of dialkyl ketones.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Bioanorganische Chemie (Ward)
UniBasel Contributors:Ward, Thomas R. R.
Item Type:Article, refereed
Article Subtype:Research Article
Note:Publication type according to Uni Basel Research Database: Journal article
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Last Modified:24 Apr 2017 11:54
Deposited On:22 Mar 2012 14:15

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