Synthesis of a Configurationally Stable Three-Legged Piano-Stool Complex

Therrien, Bruno and Ward, Thomas R.. (1999) Synthesis of a Configurationally Stable Three-Legged Piano-Stool Complex. Angewandte Chemie International Edition, 38 (3). pp. 405-408.

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Official URL: http://edoc.unibas.ch/dok/A5254483

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NA transition metal Lewis acid with metal-centered chirality is obtained by η6:η1:η1 coordination of a 1,3-disubstituted arene with a phosphane and a pyrazole tether (PArN) to ruthenium. The three-legged piano-stool complex [{η6:η1:η1-(PArN)}Ru(H2O)]2+ (structure depicted) displays remarkable configurational stability. Its planar chiral, neutral precursor [{η6:η1-(PArN)}RuCl2] can be resolved by preparative HPLC.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Bioanorganische Chemie (Ward)
UniBasel Contributors:Ward, Thomas R. R.
Item Type:Article, refereed
Article Subtype:Research Article
Note:Publication type according to Uni Basel Research Database: Journal article
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Last Modified:24 Apr 2017 14:42
Deposited On:22 Mar 2012 14:07

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