Synthesis of a Configurationally Stable Three-Legged Piano-Stool Complex

Therrien, Bruno and Koenig, Adrian and Ward, Thomas R.. (1999) Synthesis of a Configurationally Stable Three-Legged Piano-Stool Complex. Organometallics, 18 (8). pp. 1565-1568.

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Official URL: http://edoc.unibas.ch/dok/A5254482

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Anchoring a phosphine and an enantiopure camphorpyrazole tether to an arene (PArN*) yields, after η6:η1:η1 coordination to ruthenium, [{η6:η1:η1-(PArN*)}RuL]2+ as a 1:1 mixture of diastereomers. These were separated and characterized by X-ray crystallography. The structure of the R,RP,SRu diastereomer is depicted.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Bioanorganische Chemie (Ward)
UniBasel Contributors:Ward, Thomas R. R.
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:American Chemical Society
Note:Publication type according to Uni Basel Research Database: Journal article
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Last Modified:24 Apr 2017 14:40
Deposited On:22 Mar 2012 14:07

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