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The preparation and structural characterization of a chromium(III) complex with a potentially helicating ligand; the X-ray crystal structure of trans-dichloro(2,2′:6′,2″:6″,2‴-quaterpyridine-N,N′,N″,N‴)chromium(III) chloride tetrahydrate

Constable, E. C. and Elder, S. M. and Tocher, D. A.. (1992) The preparation and structural characterization of a chromium(III) complex with a potentially helicating ligand; the X-ray crystal structure of trans-dichloro(2,2′:6′,2″:6″,2‴-quaterpyridine-N,N′,N″,N‴)chromium(III) chloride tetrahydrate. Polyhedron, Vol. 11, H. 11. pp. 1337-1342.

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Official URL: http://edoc.unibas.ch/dok/A5248886

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Abstract

The reaction of 2,2′:6′,2″:6″,2‴-quaterpyridine (qpy) with chromium compounds has been investigated. Treatment with [Cr(H2O)4Cl2]Cl · 4H2O for short periods results in the formation of [H2qpy]Cl2, but prolonged reaction times allow the preparation of salts of trans-[Cr(qpy)Cl2]+. The crystal structure of the salt trans-[Cr(qpy)Cl2]Cl · 2H2O is described.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
Item Type:Article, refereed
Bibsysno:Link to catalogue
Publisher:Pergamon Press
ISSN:0277-5387
Note:Publication type according to Uni Basel Research Database: Journal article
Last Modified:22 Mar 2012 14:29
Deposited On:22 Mar 2012 14:07

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