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Adding the second dimension with cadmium : two-dimensional sheets assembled from cadmium(II) and 4 '-phenyl-4,2 ':6 ',4 ''-terpyridine and locked by pi-stacked interactions

Constable, Edwin C. and Zhang, Guoqi and Housecroft, Catherine E. and Neuburger, Markus and Zampese, Jennifer A.. (2009) Adding the second dimension with cadmium : two-dimensional sheets assembled from cadmium(II) and 4 '-phenyl-4,2 ':6 ',4 ''-terpyridine and locked by pi-stacked interactions. CrystEngComm, 11 (11). pp. 2279-2281.

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Official URL: http://edoc.unibas.ch/dok/A5251521

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Abstract

4'-Phenyl-4,2':6',4 ''-terpyridine (3) reacts with Cd(NO3)(2)center dot 4H(2)O in MeOH-CHCl3 to produce [Cd(3)(2)(ONO2)(2)center dot MeOH center dot CHCl3](n) in high yield; two sets of undulating chains built up from trans-related ligands result in the formation of two-dimensional sheets, locked together by efficient pi-stacking involving the phenyl substituents.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
UniBasel Contributors:Constable, Edwin Charles
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Royal Society of Chemistry
e-ISSN:1466-8033
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:08 May 2017 08:53
Deposited On:22 Mar 2012 14:07

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