Vanadium complexes of planar pentadentate macrocyclic ligands

Chung, L. Y. and Constable, E. C. and Khan, M. S. and Lewis, J.. (1991) Vanadium complexes of planar pentadentate macrocyclic ligands. Inorganica chimica acta, 185 (1). pp. 93-96.

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Official URL: http://edoc.unibas.ch/dok/A5248888

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Vanadium trichloride forms 1:1 adducts with 6,6`-bis(hydrazino)-2,2`-bipyridines, in which the metal is in a six-coordinate environment, with the two axial sites occupied by chloride ligands. These complexes are paramagnetic and ESR active. Condensation of these complexes with 2,6-pyridinedialdehyde leads to either vanadium (III) macrocyclic complexes or free macrocyclic ligands, depending upon the conditions of pH.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Constable)
Item Type:Article, refereed
Publisher:Elsevier Sequoia
Note:Publication type according to Uni Basel Research Database: Journal article
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Last Modified:26 Aug 2019 15:47
Deposited On:22 Mar 2012 14:06

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