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Vectorial property dependence in bis4 '-(n-pyridyl)-2,2 ': 6 ',2 ''-terpyridineiron(II) and ruthenium(II) complexes with n=2, 3 and 4

Beves, Jonathon E. and Dunphy, Emma L. and Constable, Edwin C. and Housecroft, Catherine E. and Kepert, Cameron J. and Neuburger, Markus and Price, David J. and Schaffner, Silvia. (2008) Vectorial property dependence in bis4 '-(n-pyridyl)-2,2 ': 6 ',2 ''-terpyridineiron(II) and ruthenium(II) complexes with n=2, 3 and 4. Dalton Transactions, 6 (3). pp. 386-396.

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Official URL: http://edoc.unibas.ch/dok/A5248857

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Abstract

A comparative structural and spectroscopic investigation of the complexes [M(1)(2)](2+), [M(2)(2)](2+) and [ M( 3) 2] 2+ in which M = Fe or Ru, and ligands 1, 2 and 3 are 4`-(2-pyridyl)-, 4`-(3-pyridyl)- and 4`-(4-pyridyl)-2,2`:6`,2``-terpyridine, respectively, is reported. The complexes [Ru(1)(2)](2+), [Ru(2)(2)](2+) and [Ru(3)(2)](2+) undergo mono- and bis-N-methylation. The consequences of methylation on the absorption spectra and electrochemical properties are discussed; the solid-state structure of the bis(N-methylated) derivative of [Ru(2)(2)][PF6](2) is presented.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles and Housecroft, Catherine Elizabeth
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Royal Society of Chemistry
ISSN:1477-9226
e-ISSN:1477-9234
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:12 Apr 2017 06:41
Deposited On:22 Mar 2012 14:06

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