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A supramolecularly-caged ionic iridium (III) complex yielding bright and very stable solid-state light-emitting electrochemical cells

Graber, Stefan and Doyle, Kevin and Neuburger, Markus and Housecroft, Catherine E. and Constable, Edwin C. and Costa, Ruben D. and Orti, Enrique and Repetto, Diego and Bolink, Henk J.. (2008) A supramolecularly-caged ionic iridium (III) complex yielding bright and very stable solid-state light-emitting electrochemical cells. Journal of the American Chemical Society, 130 (45). pp. 14944-14945.

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Official URL: http://edoc.unibas.ch/dok/A5251865

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Abstract

A new iridium(III) complex showing intramolecular interligand pi-stacking has been synthesized and used to improve the stability of single-component, solid-state light-emitting electrochemical cell (LEC) devices. The pi-stacking results in the formation of a very stable supramolecularly caged complex. LECs using this complex show extraordinary stabilities (estimated lifetime of 600 h) and luminance values (average luminance of 230 cd m-2) indicating the path toward stable ionic complexes for use in LECs reaching stabilities required for practical applications.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles and Neuburger, Markus and Housecroft, Catherine Elizabeth
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:American Chemical Society
ISSN:0002-7863
e-ISSN:1520-5126
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:12 Apr 2017 07:04
Deposited On:22 Mar 2012 14:06

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