The Introduction of Asymmetry into Alkyl-Decorated Fréchet-Type Dendrons

Constable, Edwin C. and Graber, Stefan and Hermann, Bianca A. and Housecroft, Catherine E. and Malarek, Michael S. and Scherer, Lukas J.. (2008) The Introduction of Asymmetry into Alkyl-Decorated Fréchet-Type Dendrons. European Journal of Organic Chemistry, 2009 (15). pp. 2644-2651.

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Official URL: http://edoc.unibas.ch/dok/A5251870

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A strategy for the introduction of asymmetry into Fréchet-type dendrons bearing n-alkyl chains is described. Starting from a methyl 3,5-dihydroxybenzoate core, 3,5-bis(octyloxyphenyl)methoxy and 3,5-bis(alkoxyphenyl)methoxy units are introduced in a stepwise manner. The method is illustrated by the syntheses of four representative compounds having mixed n-octyl/n-butyl, n-octyl/n-hexyl, n-octyl/n-heptyl and n-octyl/n-dodecyl substituents. The new compounds have been characterized by spectroscopic and mass spectrometric techniques.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Constable)
UniBasel Contributors:Constable, Edwin Charles and Housecroft, Catherine Elizabeth and Graber, Stefan
Item Type:Article, refereed
Article Subtype:Research Article
Note:Publication type according to Uni Basel Research Database: Journal article
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Last Modified:10 May 2017 07:14
Deposited On:22 Mar 2012 14:06

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