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Exploiting the second coordination sphere : proteins as host for enantioselective catalysis

Ward, Thomas R. and Collot, Jerome and Gradinaru, Julieta and Loosli, Andreas and Skander, Myriem and Letondor, Christophe and Joseph, Edith and Klein, Gerard. (2003) Exploiting the second coordination sphere : proteins as host for enantioselective catalysis. Chimia, 57 (10). pp. 586-588.

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Official URL: http://edoc.unibas.ch/dok/A5254503

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Abstract

With the aim of exploring the role of the second coordination sphere in enantioselective catalysis, achiral organometallic catalyst precursors are anchored in proteins via non-covalent interactions. A chemogenetic procedure allows the activity and the enantioselectivity of the artificial metalloenzymes to be optimized, to yield hybrid catalysts with features reminiscent both of enzymatic and homogeneous catalysts.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Bioanorganische Chemie (Ward)
UniBasel Contributors:Ward, Thomas R. R.
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Schweizerische Chemische Gesellschaft
ISSN:0009-4293
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
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Last Modified:24 Apr 2017 14:15
Deposited On:22 Mar 2012 14:06

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