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Items where Division is "05 Faculty of Science > Departement Chemie > Chemie > Synthetische organische Chemie (Pfaltz)"

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Number of items at this level: 100.

2016

Isenegger, Patrick G.. Asymmetric Morita-Baylis-Hillmann reaction : catalyst development and mechanistic insights based on mass spectrometric back reaction screening. 2016, PhD Thesis, University of Basel, Faculty of Science.

Isenegger, Patrick G. and Bächle, Florian and Pfaltz, Andreas. (2016) Asymmetric Morita-Baylis-Hillman Reaction: Catalyst Development and Mechanistic Insights Based on Mass Spectrometric Back-Reaction Screening. Chemistry - A European Journal, 22 (49). pp. 17595-17599.

Isenegger, Patrick G. and Pfaltz, Andreas. (2016) Mass Spectrometric Back Reaction Screening of Quasi-Enantiomeric Products as a Mechanistic Tool. Chemical Record, 16 (6). pp. 2534-2543.

Padevět, Jaroslav and Schrems, Marcus G. and Scheil, Robin and Pfaltz, Andreas. (2016) NeoPHOX - a structurally tunable ligand system for asymmetric catalysis. Beilstein Journal of Organic Chemistry, 12. pp. 1185-1195.

Scheil, Robin. Iridium-Catalyzed asymmetric hydrogenation : A: Studies on the synthesis of pyrazine-based P,N Ligands, B: Diastereoselective hydrogenation of chiral cyclohexenes. 2016, PhD Thesis, University of Basel, Faculty of Science.

2015

Auth, Johanna. Dihydrogen activation at non-metallic centers. 2015, PhD Thesis, University of Basel, Faculty of Science.

Auth, Johanna and Padevet, Jaroslav and Mauleón, Pablo and Pfaltz, Andreas. (2015) Pyridylidene-mediated dihydrogen activation coupled with catalytic imine reduction. Angewandte Chemie International Edition, 54 (33). pp. 9542-9545.

Bächle, Florian and Fleischer, Ivana and Pfaltz, Andreas. (2015) Mass Spectrometric Screening of Racemic Amine Catalysts for Enantioselective Michael Additions. Advanced synthesis & catalysis, 357 (10). pp. 2247-2254.

Laupheimer, Charlotte. Desymmetrisierung von substituierten cyclohexa-1, 4-dienen mittels enantioselektiver monohydrierung. 2015, PhD Thesis, University of Basel, Faculty of Science.

Oliveira, Caio C. and Pfaltz, Andreas and Correia, Carlos Roque Duarte. (2015) Quaternary Stereogenic Centers through Enantioselective Heck Arylation of Acyclic Olefins with Aryldiazonium Salts: Application in a Concise Synthesis of (R)-Verapamil. Angewandte Chemie International Edition, 54 (47). pp. 14036-14039.

Pauli, Larissa and Tannert, René and Scheil, Robin and Pfaltz, Andreas. (2015) Asymmetric hydrogenation of furans and benzofurans with iridium-pyridine-phosphinite catalysts. Chemistry : a European journal, 21 (4). pp. 1482-1487.

2014

Auth, Johanna and Mauleon, Pablo and Pfaltz, Andreas. (2014) Synthesis of functionalized pyridinium salts bearing a free amino group. Arkivoc, 2014 (3). pp. 154-169.

Bernasconi, Maurizio. New subtrate classes in iridium-catalyzed asymmetric hydrogenation. 2014, PhD Thesis, University of Basel, Faculty of Science.

Bernasconi, Maurizio and Müller, Marc-André and Pfaltz, Andreas. (2014) Asymmetric hydrogenation of maleic acid diesters and anhydrides. Angewandte Chemie International Edition, 53 (21). pp. 5385-5388.

Bernasconi, Maurizio and Ramella, Vincenzo and Tosatti, Paolo and Pfaltz, Andreas. (2014) Iridium-catalyzed asymmetric hydrogenation of 3,3-disubstituted allylic alcohols in ethereal solvents. Chemistry - A European Journal, 20 (9). pp. 2440-2444.

Bächle, Florian. Determining the enantioselectivity of chiral catalysts - mass spectrometry as a mechanistic and screening tool. 2014, PhD Thesis, University of Basel, Faculty of Science.

Gruber, Stefan and Pfaltz, Andreas. (2014) Asymmetric hydrogenation with iridium C,N and N,P ligand complexes : characterization of dihydride intermediates with a coordinated alkene. Angewandte Chemie International Edition, 53 (7). pp. 1896-1900.

Gsellinger, Heiko. Combining NMR spectroscopy and organic synthesis : from small building blocks to large biomolecules. 2014, PhD Thesis, University of Basel, Faculty of Science.

Müller, Marc-André. Study of chiral iridium N,P ligand complexes as catalysts for the asymmetric hydrogenation of different substrate classes. 2014, PhD Thesis, University of Basel, Faculty of Science.

Müller, Marc-André and Pfaltz, Andreas. (2014) Asymmetric hydrogenation of α,β-unsaturated nitriles with base-activated iridium N,P ligand complexes. Angewandte Chemie International Edition, 53 (33). pp. 8668-8671.

Parmentier, Michael and Hartung, Thomas and Pfaltz, Andreas and Muri, Dieter. (2014) Iridium-catalyzed H/D exchange : ligand complexes with improved efficiency and scope. Chemistry - A European Journal, 20 (36). pp. 11496-11504.

Pauli, Larissa. Iridium-catalyzed asymmetric hydrogenation of furan derivatives and thiophene 1,1-dioxides. 2014, PhD Thesis, University of Basel, Faculty of Science.

Pischl, Matthias C. and Weise, Christian F. and Haseloff, Stefan and Müller, Marc-André and Pfaltz, Andreas and Schneider, Christoph. (2014) A Highly Stereoselective and Flexible Strategy for the Convergent Synthesis of Long-Chain Polydeoxypropionates: Application towards the Synthesis of the Glycolipid Membrane Components Hydroxyphthioceranic and Phthioceranic Acid. Chemistry - A European Journal, 20 (52). pp. 17360-17374.

Schmid, Fabian and Bernasconi, Maurizio and Jessen, Henning J. and Pfaltz, Andreas and Gademann, Karl. (2014) Catalytic Enantioselective Total Synthesis of (–)-Pyridovericin. Synthesis, 46 (07). pp. 864-870.

2013

Bächle, Florian and Duschmalé, Jörg and Ebner, Christian and Pfaltz, Andreas and Wennemers, Helma. (2013) Organocatalytic Asymmetric Conjugate Addition of Aldehydes to Nitroolefins : Identification of Catalytic Intermediates and the Stereoselectivity-Determining Step by ESI-MS. Angewandte Chemie International Edition, 52 (48). pp. 12619-12623.

D. J. Frank, A. Franzke and Pfaltz, A.. (2013) Asymmetric Hydrogenation Using Rhodium Complexes Generated from Mixtures of Monodentate Neutral and Anionic Phosphorus Ligands. Chemistry, a European journal, Vol. 18. S. 2405-2415.

Ganic, Adnan. Iridium-catalyzed asymmetric hydrogenation : development of New N,P ligands and hydrogenation of alkenyl boronic esters. 2013, PhD Thesis, University of Basel, Faculty of Science.

Gruber, Stefan and Neuburger, Markus and Pfaltz, Andreas. (2013) Characterization and Reactivity Studies of Dinuclear Iridium Hydride Complexes Prepared from Iridium Catalysts with N,P and C,N Ligands Under Hydrogenation Conditions. Organometallics, 32 (16). pp. 4702-4711.

Padevet, Jaroslav. Synthesis of new phosphino-oxazoline ligands for asymmetric catalysis. 2013, PhD Thesis, University of Basel, Faculty of Science.

Pischl, Matthias C. and Weise, Christian F. and Müller, Marc-André and Pfaltz, Andreas and Schneider, Christoph. (2013) A convergent and stereoselective synthesis of the glycolipid components phthioceranic acid and hydroxyphthioceranic acid. Angewandte Chemie International Edition, 52 (34). pp. 8968-8972.

Schramm, York. Synthetic and mechanistic investigations of iridium-catalysed imine hydrogenation. 2013, PhD Thesis, University of Basel, Faculty of Science.

Schramm, York and Barrios-Landeros, Fabiola and Pfaltz, Andreas. (2013) Discovery of an Iridacycle Catalyst with Improved Reactivity and Enantioselectivity in the Hydrogenation of Dialkyl Ketimines. Chemical Science, 4. pp. 2760-2766.

Schumacher, Andreas and Bernasconi, Maurizio and Pfaltz, Andreas. (2013) Chiral N-heterocyclic carbene/pyridine ligands for the iridium-catalyzed asymmetric hydrogenation of olefins. Angewandte Chemie International Edition, 52 (29). pp. 7422-7425.

Spahn, Elizabeth and Albright, Abigail and Shevlin, Michael and Pauli, Larissa and Pfaltz, Andreas and Gawley, Robert E.. (2013) Double-asymmetric hydrogenation strategy for the reduction of 1,1-diaryl olefins applied to an improved synthesis of CuIPhEt, a C2-symmetric N-heterocyclic carbenoid. Journal of Organic Chemistry, 78 (6). pp. 2731-2735.

Stoessel Tran-Van, Anne-Florence. Reactivity of strained systems in alkyne cycloaddition reactions - synthesis of substituted cycloparaphenylenes. 2013, PhD Thesis, University of Basel, Faculty of Science.

2012

Blaser, Hans-Ulrich and Pfaltz, Andreas and Wennemers, Helma. (2012) Chiral Compounds. In: Ullmann's Encyclopedia of Industrial Chemistry. Weinheim, p. 26.

Ebner, Christian. Development and evaluation of chiral catalysts for asymmetric C-C and C-H bond forming reactions. 2012, PhD Thesis, University of Basel, Faculty of Science.

Ganic, Adnan and Pfaltz, Andreas. (2012) Iridium-Catalyzed Enantioselective Hydrogenation of Alkenylboronic Esters. Chemistry - A European Journal, 18 (22). pp. 6724-6728.

Ganic, Adnan and Rageot, Denise and Tröndlin, Lars and Pfaltz, Andreas. (2012) Recent Advances in Iridium-Catalyzed Asymmetric Hydrogenation : New Catalysts, Substrates and Applications in Total Synthesis. Chimia, 66 (4). pp. 187-191.

Kessler, Simon Niklaus. Development of a bidentate lewis acid catalyzed inverse electron demand diels-alder reaction of 1,2-diazines for the synthesis of substituted arenes. 2012, PhD Thesis, University of Basel, Faculty of Science.

Kölbl, Dominikus. Spins, disorder and interactions in GaAs and graphene. 2012, PhD Thesis, University of Basel, Faculty of Science.

Pfaltz, Andreas. (2012) Comment 2 on "An overview of recent developments in metal-catalyzed asymmetric transformations" by Sandovai and Noyori. In: Organic chemistry : breakthroughs and perspectives. Weinheim, pp. 363-365.

Rageot, Denise. Chiral proline-based ligands for iridium-catalyzed asymmetric hydrogenation. 2012, PhD Thesis, University of Basel, Faculty of Science.

Rageot, Denise and Pfaltz, Andreas. (2012) Chiral Proline-Based P,O and P,N Ligands for Iridium-Catalyzed Asymmetric Hydrogenation. Helvetica Chimica Acta, 95 (11). pp. 2176-2193.

Richoz, Stéphanie Angèle. Palladium-catalyzed enantioselective allylic substitutions on bifunctional substrates. 2012, PhD Thesis, University of Basel, Faculty of Science.

Schumacher, Andreas. Untersuchungen zur asymmetrischen, Iridium-katalysierten Hydrierung konjugierter Diene und Anwendungen in der Naturstoffsynthese. 2012, PhD Thesis, University of Basel, Faculty of Science.

Tannert, René and Pfaltz, Andreas. (2012) 6. Mixed Donor Ligands. In: Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis. Chichester, pp. 233-265.

Woodmansee, David H. and Müller, Marc-Andé and Tröndlin , Lars and Hörmann, Esther and Pfaltz, Andreas. (2012) Asymmetric Hydrogenation of α,β-Unsaturated Carboxylic Esters with Chiral Iridium N,P Ligand Complexes. Chemistry - A European Journal, 18 (43). pp. 13780-13786.

2011

Basler, Jonathan Michael. Method development, synthesis and mechanistic investigations of heteroaromatic compounds. 2011, PhD Thesis, University of Basel, Faculty of Science.

Bausch, Cory and Pfaltz, Andreas. (2011) 6. PHOX Ligands. In: Privileged chiral ligands and catalysts. Weinheim, pp. 221-256.

Ebner, Christian and Müller, Constanze A. and Markert, Christian and Pfaltz, Andreas. (2011) Determining the enantioselectivity of chiral catalysts by mass spectrometric screening of their racemic forms. Journal of the American Chemical Society, 133 (13). pp. 4710-4713.

Ebner, Christian and Pfaltz, Andreas. (2011) Chiral dihydrobenzo[1,4]oxazines as catalysts for the asymmetric transfer hydrogenation of α,β-unsaturated aldehydes. Tetrahedron, 67. pp. 10827-10290.

Frank, Dominik. Chirale mono- und bidentate Phosphorliganden für die enantioselektive Metall-katalysierte Hydrierung. 2011, PhD Thesis, University of Basel, Faculty of Science.

Franzke, Axel and Pfaltz, Andreas. (2011) Zwitterionic Iridium Complexes with P,N-Ligands as Catalysts for the Asymmetric Hydrogenation of Alkenes. Chemistry - A European Journal, 17 (15). pp. 4131-4144.

Franzke, Axel and Voss, Felix and Pfaltz, Andreas. (2011) Synthesis of new serine-based phosphinooxazoline ligands and iridium complexes for asymmetric hydrogenations. Tetrahedron, 67 (24). pp. 4358-4363.

Rageot, Denise and Woodmansee, David H. and Pugin, Benoît and Pfaltz, Andreas. (2011) Proline Based P,O Iridium Complexes as Highly Selective Catalysts in the Asymmetric Hydrogenation of Trisubstituted Alkenes. Angewandte Chemie International Edition, 50 (41). pp. 9598-9601.

Reuter, Raphael. Synthesis, properties and applications of macrocyclic azobenzenes. 2011, PhD Thesis, University of Basel, Faculty of Science.

Schumacher, Andreas and Jessen, Henning J. and Schmid, Fabian and Pfaltz, Andreas and Gademann, Karl. (2011) Catalytic Enantioselective Total Synthesis of (+)-Torrubiellone. Organic Letters, 13 (16). pp. 4368-4370.

Schumacher, Andreas and Jessen, Henning J. and Shaw, Trawis and Pfaltz, Andreas and Gademann, Karl. (2011) A Unified Approach for the Stereoselective Total Synthesis of Pyridone Alkaloids and Their Neuritogenic Activity. Angewandte Chemie International Edition, 50 (18). pp. 4222-4226.

Schumacher, Andreas and Schrems, Markus and Pfaltz, ANdreas. (2011) Enantioselective Synthesis of cis-1,2-Disubstituted Cyclopentanes and Cyclohexanes by Suzuki–Miyaura Cross-Coupling and Iridium-Catalyzed Asymmetric Hydrogenation. Chemistry - A European Journal, 17 (48). pp. 13502-13509.

Tröndlin, Lars. Entwicklung neuer P,N-Liganden und ihre Anwendungen in der Iridium-katalysierten Hydrierung von α,β-ungesättigten Carbonsäureestern. 2011, PhD Thesis, University of Basel, Faculty of Science.

Wang, Aie and Fraga, Rui P. A. and Hörmann, Esther and Pfaltz, Andreas. (2011) Iridium-Catalyzed Asymmetric Hydrogenation of Unfunctionalized, Trialkyl-Substituted Olefins. Chemistry - An Asian Journal, 6 (2). pp. 599-606.

Weise, Christian F. and Pischl, Matthias and Pfaltz, Andreas and Schneider, Christioph. (2011) A non-iterative, flexible, and highly stereoselective synthesis of polydeoxypropionates - synthesis of (+)-vittatalactone. Chemical Communications, 47 (11). pp. 3248-3250.

Woodmansee, David H. and Pfaltz, Andreas. (2011) Iridium-Catalyzed Asymmetric Hydrogenation of Olefins with Chiral N,P and C,N Ligands. In: Iridium Catalysis. Berlin, pp. 31-76.

Woodmansee, David H. and Pfaltz, Andreas.. (2011) Asymmetric hydrogenation of alkenes lacking coordinating groups. Chemical Communications, 47 (28). pp. 7912-7916.

2010

Baeza, Alejandro and Pfaltz, Andreas. (2010) Iridium-Catalyzed Asymmetric Hydrogenation of Imines. Chemistry - A European Journal, 16 (13). pp. 4003-4009.

Baeza, Alejandro and Pfaltz, Andreas. (2010) Iridium-Catalyzed Asymmetric Hydrogenation of N-Protected Indoles. Chemistry - A European Journal, 16 (7). pp. 2036-2039.

Fleischer, Ivana. Combinatorial organocatalyst development and screening of conjugate additions. 2010, PhD Thesis, University of Basel, Faculty of Science.

Fleischer, Ivana and Pfaltz, Andreas. (2010) Enantioselective Michael Addition to α,β-Unsaturated Aldehydes: Combinatorial Catalyst Preparation and Screening, Reaction Optimization, and Mechanistic Studies. Chemistry - A European Journal, 16 (1). pp. 95-99.

H. Landert, F. Spindler and A. Wyss, H. -U. Blaser and B. Pugin, Y. Ribourduoille and B. Gschwend, B. Ramalingam and Pfaltz, A.. (2010) Chiral Mixed Secondary Phosphine Oxide (SPO)-Phosphines : High Performing and Easily Accessible Ligands For Asymmetric Hydrogenation. Angewandte Chemie. International edition in English, Vol. 49. S. 6873-6876.

Liniger, Marc and Gschwend, Björn and Neuburger, Markus and Schaffner, Silvia and Pfaltz, Andreas. (2010) Unprecedented Reactivity of Iridium(I) Secondary Phosphine Oxide Complexes: Formation of P-Coordinated Phosphinate Complexes by P−Aryl Bond Cleavage. Organometallics, 29 (22). pp. 5993-5958.

Lotz, M. and Pugin, B. and Kesselgruber, M. and M. Thomme, F. Spindler and Pfaltz, A. and Schönleber, M.. (2010) Bis(2-methoxymethyl)pyrrolidine)phosphine as Effective Chiral Auxiliary for the Stereo¬selective Synthesis of Chiral Ferrocenyl Diphosphines. Tetrahedron. Asymmetry, Vol. 21 , H. 9-10, S. 1199–1202.

Schärer, Claude André. Palladium-katalysierte enantioselektive allylische Aminierung von α,β-ungesättigten Carbonsäurederivaten. 2010, PhD Thesis, University of Basel, Faculty of Science.

Tiefenbacher, Konrad and Tröndlin, Lars and Pfaltz, Andreas and Mulzer, Johann. (2010) An Expeditious Asymmetric Formal Synthesis of the Antibiotic Platensimycin. Tetrahedron, 66 (33). pp. 6508-6513.

Woodmansee, David and Müller, Marc-André and Pfaltz, Andreas. (2010) Chiral Pyridyl Phosphinites with Large Aryl Substituents as Efficient Ligands for the Asymmetric Iridium-Catalyzed Hydrogenation of Difficult Substrates. Chemical Science, 2010 (1). pp. 72-78.

Woodmansee, David Harrison. Chiral pyridyl phosphinite catalysts and the development of structure selectivity relationships in the asymmetric hydrogenation of trisubstituted alkenes. 2010, PhD Thesis, University of Basel, Faculty of Science.

Yoshinari, T. and Ohmori, K. and Schrems, M. G. and Pfaltz, A. and Suzuki, K.. (2010) Total Synthesis and Absolute Configuration of Macrocidin A, a Cyclophane Tetramic Acid Natural Product. Angewandte Chemie. International edition in English, Vol. 49, H. 5 , p. 881–885.

2009

G. G. Bianco, M. C. Ferraz and A. M. Costa, L. V. Costa-Lotufo and C. Pessoa, M. O. de Moraes and M. G. Schrems, A. Pfaltz and L. F. Silva, Jr.. (2009) (+)- and (-)-Mutisianthol : first total synthesis, absolute configuration, and antitumor activity. The journal of organic chemistry, Vol. 74, H. 6. S. 2561-2566.

Gschwend, Björn. P-Chiral phosphorus ligands. synthesis and application in asymmetric hydrogenation. 2009, PhD Thesis, University of Basel, Faculty of Science.

Gschwend, Björn and Pugin, Benoît and Bertogg, Andreas and Pfaltz, Andreas. (2009) P-Chiral Ferrocenephospholanes: Synthesis, Reactivity, Metal Complex Chemistry and Application in the Asymmetric Hydrogenation of Olefins. Chemistry - A European Journal, 15 (47). pp. 12993-13007.

Maywald, Matthias and Pfaltz, Andreas. (2009) Chromatography-Free Enzymatic Kinetic Resolution of Secondary Alcohols. Synthesis, 2009 (21). pp. 3654-3660.

Müller, Constanze and Markert, Christian and Teichert, Antje and Pfaltz, Andreas. (2009) Mass Spectrometric Screening of Chiral Catalysts and Catalyst Mixtures. Chemical Communications, 45 (13). pp. 1607-1618.

Pfaltz, Andreas and Baeza, Alejandro. (2009) Iridium-Catalyzed Asymmetric Hydrogenation of Unfunctionalized Enamines. Chemistry - A European Journal, 15 (10). pp. 2266-2269.

Schrems, Marcus G. and Pfaltz, Andreas. (2009) NeoPHOX – an easily accessible P,N ligand for Iridium-catalyzed asymmetric hydrogenation : preparation, scope and application in the synthesis of Demethyl Methoxycalamenene. Chemical Communications, 45 (41). pp. 6210-6212.

Schrems, Marcus Georg. Iridium-katalysierte Hydrierung unfunktionalisierter Olefine. 2009, PhD Thesis, University of Basel, Faculty of Science.

2008

Müller, Constanze Annelie. Mass spectrometric screening of chiral catalysts by monitoring the back reaction : palladium-catalysed allylic substitution. 2008, PhD Thesis, University of Basel, Faculty of Science.

Toussaint, Aurélie. Boron-Bridged Bis(oxazolines) and their use in copper-catalyzed reactions. 2008, PhD Thesis, University of Basel, Faculty of Science.

2007

Teichert, Antje Maria. Screening of chiral Diels-Alder catalysts by mass spectrometric monitoring of the retro reaction. 2007, PhD Thesis, University of Basel, Faculty of Science.

2006

Bulic, Bruno. Palladium and copper-catalysed (C-C)-bond formation. 2006, PhD Thesis, University of Basel, Faculty of Science.

Franzke, Axel. Zwitterionische Iridiumkomplexe als Katalysatoren für enantioselektive Hydrierungen. 2006, PhD Thesis, University of Basel, Faculty of Science.

Langer, Michael. Immobilisierung von chiralen Hydrierkatalysatoren auf Goldkolloiden. 2006, PhD Thesis, University of Basel, Faculty of Science.

Neumann, Eva. Transition metal complexes with P,N-ligands and silylenes : synthesis and catalytic studies. 2006, PhD Thesis, University of Basel, Faculty of Science.

Stohler, Remo. Asymmetric metal-catalyzed [3+2] cycloadditions of azomethine ylides. 2006, PhD Thesis, University of Basel, Faculty of Science.

2005

Kaiser, Stefan. Neue Phosphor-Pyridin-Liganden für die Iridium-katalysierte enantioselektive Hydrierung. 2005, PhD Thesis, University of Basel, Faculty of Science.

Köhler, Valentin. Neue ionische Liganden für Übergangsmetallkomplexe und deren Anwendung in der asymmetrischen Katalyse. 2005, PhD Thesis, University of Basel, Faculty of Science.

Markert, Christian. Screening chiraler Katalysatoren durch massenspektrometrische Erfassung katalytischer Intermediate. 2005, PhD Thesis, University of Basel, Faculty of Science.

Nanchen, Steve. N-heterocyclic carbene ligands for iridium-catalysed asymmetric hydrogenation. 2005, PhD Thesis, University of Basel, Faculty of Science.

Schönleber, Marc. Chirale P,N- und P,P-Liganden : Synthese und Anwendungen in der asymmetrischen Katalyse. 2005, PhD Thesis, University of Basel, Faculty of Science.

2004

Belser, Thomas. Verankerung von Rhodium-Hydrierkatalysatoren an Alkylthiolat-beschichtete Goldkolloide. 2004, PhD Thesis, University of Basel, Faculty of Science.

Menges, Frederik. Neue modulare P,N-Liganden für die Iridium-katalysierte asymmetrische Hydrierung. 2004, PhD Thesis, University of Basel, Faculty of Science.

This list was generated on Mon May 1 03:48:36 2017 CEST.