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2023

Guo, Shu-Min and Huh, Soohee and Coehlo, Max and Shen, Li and Pieters, Grégory and Baudoin, Olivier. (2023) A C-H activation-based enantioselective synthesis of lower carbo[n]helicenes. Nature chemistry, 15. pp. 872-880.

Martynova, Ekaterina A. and Zuccarello, Marco and Kronenberg, Domenic and Beliš, Marek and Czapik, Agnieszka and Zhang, Ziyun and Van Hecke, Kristof and Kwit, Marcin and Baudoin, Olivier and Cavallo, Luigi and Nolan, Steven P.. (2023) Simple synthetic access to [Au(IBiox)Cl] complexes. Dalton Transactions, 52 (22). pp. 7558-7563.

Geraci, Andrea and Stojiljković, Uros and Antien, Kevin and Salameh, Nihad and Baudoin, Olivier. (2023) Iridium(III)-Catalyzed Intermolecular C(sp³)-H Amidation for the Synthesis of Chiral 1,2-Diamines. Angewandte Chemie International Edition, 62 (42). e202309263.

Wheatley, Matthew and Zuccarello, Marco and Tsitopoulou, Maria and Macgregor, Stuart A. and Baudoin, Olivier. (2023) Effect of α-Substitution on the Reactivity of C(sp³)–H Bonds in Pd⁰-Catalyzed C–H Arylation. ACS Catalysis, 13. pp. 12563-12570.

Kudashev, Anton and Vergura, Stefania and Zuccarello, Marco and Bürgi, Thomas and Baudoin, Olivier. (2023) Methylene C(sp3)−H Arylation Enables the Stereoselective Synthesis and Structure Revision of Indidene Natural Products. Angewandte Chemie International Edition. Online ahead of print.

2022

Miyakoshi, Takeru and Niggli, Nadja E. and Baudoin, Olivier. (2022) Remote Construction of N-Heterocycles via 1,4-Palladium Shift-Mediated Double C-H Activation. Angewandte Chemie International Edition, 61 (17). e202116101.

Ferlin, Francesco and Anastasiou, Ioannis and Salameh, Nihad and Miyakoshi, Takeru and Baudoin, Olivier and Vaccaro, Luigi. (2022) C(sp³)−H Arylation Promoted by a Heterogeneous Palladium-N-Heterocyclic Carbene Complex in Batch and Continuous Flow. ChemSusChem, 15 (6). e202102736.

2021

Vyhivskyi, Oleksandr and Kudashev, Anton and Miyakoshi, Takeru and Baudoin, Olivier. (2021) Chiral Catalysts for Pd-0-Catalyzed Enantioselective C-H Activation. Chemistry - A European Journal, 27 (4). pp. 1231-1257.

Savary, David and Baudoin, Olivier. (2021) Enantioselective Pd0-Catalyzed C(sp2)-H Arylation for the Synthesis of Chiral Warped Molecules. Angewandte Chemie International Edition. 10.1002/anie.202013303.

Melot, Romain and Zuccarello, Marco and Cavalli, Diana and Niggli, Nadja and Devereux, Michael and Bürgi, Thomas and Baudoin, Olivier. (2021) Palladium(0)-Catalyzed Enantioselective Intramolecular Arylation of Enantiotopic Secondary C-H Bonds. Angewandte Chemie International Edition. 10.1002/anie.202014605.

Niggli, Nadja E. and Baudoin, Olivier. (2021) Design of Chiral NHC-Carboxylates as Potential Ligands for Pd-Catalyzed Enantioselective C-H Activation. Helvetica Chimica Acta, 104. e2100015.

Antien, Kevin and Geraci, Andrea and Parmentier, Michael and Baudoin, Olivier. (2021) A New Dioxazolone for the Synthesis of 1,2-Aminoalcohols via Iridium(III)-Catalyzed C(sp; 3; )-H Amidation. Angewandte Chemie International Edition, 60 (42). pp. 22948-22955.

Kudashev, Anton and Baudoin, Olivier. (2021) Site-Selective Pd-Catalyzed C(sp3)-H Arylation of Heteroaromatic Ketones. Chemistry - A European Journal, 27 (70). pp. 17688-17694.

Baudoin, Olivier. (2021) A Personal Account on Industrial Collaborations in the Field of C-H Activation. Chimia, 75 (11). pp. 967-971.

2020

Nguyen, Qui-Hien and Guo, Shu-Min and Royal, Titouan and Baudoin, Olivier and Cramer, Nicolai. (2020) Intermolecular Palladium(0)-Catalyzed Atropo-enantioselective C-H Arylation of Heteroarenes. Journal of American Chemical Society, 142 (5). pp. 2161-2167.

Baudoin, Olivier. (2020) Multiple Catalytic C-H Bond Functionalization for Natural Product Synthesis. Angewandte Chemie (International ed. in English). 10.1002/anie.202001224.

Carny, Tomas and Rocaboy, Ronan and Clemenceau, Antonin and Baudoin, Olivier. (2020) Synthesis of Amides and Esters by Palladium(0)-Catalyzed Carbonylative C(sp3)-H Activation. Angewandte Chemie International Edition, 59 (43). pp. 18980-18984.

Clemenceau, Antonin and Thesmar, Pierre and Gicquel, Maxime and Le Flohic, Alexandre and Baudoin, Olivier. (2020) Direct Synthesis of Cyclopropanes from gem-Dialkyl Groups through Double C-H Activation. Journal of the American Chemical Society, 142 (36). pp. 15355-15361.

Baumgartner, Yann and Baudoin, Olivier. (2020) One-Pot Alkene Hydroboration/Palladium-Catalyzed Migratory Suzuki−Miyaura Cross-Coupling. ACS Catalysis, 10. pp. 10508-10515.

Thesmar, Pierre and Coomar, Seemon and Prescimone, Alessandro and Häussinger, Daniel and Gillingham, Dennis and Baudoin, Olivier. (2020) Divergent Synthesis of Bioactive Dithiodiketopiperazine Natural Products Based on a Double C(sp3)−H Activation Strategy. Chemistry - A European Journal, 26.

2019

Melot, Romain and Craveiro, Marcus V. and Burgi, Thomas and Baudoin, Olivier. (2019) Divergent Enantioselective Synthesis of (Nor)illudalane Sesquiterpenes via Pd-0-Catalyzed Asymmetric C(sp(3))-H Activation. Organic Letters, 21 (3). pp. 812-815.

Royal, Titouan and Baudoin, Olivier. (2019) Pd-catalyzed gamma-arylation of gamma,delta-unsaturated O-carbamates via an unusual haptotropic rearrangement. Chemical Science, 10 (8). pp. 2331-2335.

Rocaboy, Ronan and Baudoin, Olivier. (2019) 1,4-Palladium Shift/C(sp(3))-H Activation Strategy for the Remote Construction of Five-Membered Rings. Organic Letters, 21 (5). pp. 1434-1437.

Thesmar, Pierre and Baudoin, Olivier. (2019) Efficient and Divergent Total Synthesis of (-)-Epicoccin G and (-)-Rostratin A Enabled by Double C(sp; 3; )-H Activation. Journal of the American Chemical Society, 141. pp. 15779-15783.

Rocaboy, Ronan and Anastasiou, Ioannis and Baudoin, Olivier. (2019) Redox-Neutral Coupling between Two C(sp3)-H Bonds Enabled by 1,4-Palladium Shift for the Synthesis of Fused Heterocycles. Angewandte Chemie International Edition, 58 (41). pp. 14625-14628.

Melot, Romain and Craveiro, Marcus V. and Baudoin, Olivier. (2019) Total Synthesis of (Nor)illudalane Sesquiterpenes Based on a C(sp3)-H Activation Strategy. Journal of Organic Chemistry, 84. pp. 12933-12945.

Lin, Weilong and Zhang, Ke-Feng and Baudoin, Olivier. (2019) Regiodivergent enantioselective C-H functionalization of Boc-1,3-oxazinanes for the synthesis of beta(2)- and beta(3)-amino acids. Nature Catalysis , 2 (10). pp. 882-888.

2018

Yang, Lei and Neuburger, Markus and Baudoin, Olivier. (2018) Chiral Bifunctional Phosphine-Carboxylate Ligands for Palladium(0)-Catalyzed Enantioselective C-H Arylation. Angewandte Chemie International Edition, 57 (5). pp. 1394-1398.

Zhang, Ke-Feng and Christoffel, Fadri and Baudoin, Olivier. (2018) Barbier-Negishi Coupling of Secondary Alkyl Bromides with Aryl and Alkenyl Triflates and Nonaflates. Angewandte Chemie International Edition, 57 (7). pp. 1982-1986.

Rocaboy, Ronan and Dailler, David and Baudoin, Olivier. (2018) A Four-Step Synthesis of (±)-γ-Lycorane via Pd0-Catalyzed Double C(sp2)–H/C(sp3)–H Arylation. Organic Letters, 20 (3). pp. 772-775.

Rocaboy, Ronan and Dailler, David and Zellweger, Florian and Neuburger, Markus and Salomé, Christophe and Clot, Eric and Baudoin, Olivier. (2018) Domino Pd0-Catalyzed C(sp3)-H Arylation/Electrocyclic Reactions via Benzazetidine Intermediates. Angewandte Chemie International Edition, 57 (37). pp. 12131-12135.

2017

Yang, Lei and Melot, Romain and Neuburger, Markus and Baudoin, Olivier. (2017) Palladium(0)-catalyzed asymmetric C(sp3)–H arylation using a chiral binol-derived phosphate and an achiral ligand. Chemical Science, 8 (2). pp. 1344-1349.

Goutierre, Anne-Sophie and Trinh, Huu Vinh and Larini, Paolo and Jazzar, Rodolphe and Baudoin, Olivier. (2017) Comparative Structural Analysis of Biarylphosphine Ligands in Arylpalladium Bromide and Malonate Complexes. Organometallics, 36 (1). pp. 129-135.

Royal, Titouan and Baumgartner, Yann and Baudoin, Olivier. (2017) Enantioselective α-Arylation of O-Carbamates via Sparteine-Mediated Lithiation and Negishi Cross-Coupling. Organic Letters, 19 (1). pp. 166-169.

Baudoin, Olivier. (2017) Ring Construction by Palladium(0)-Catalyzed C(sp(3))-H Activation. Accounts of Chemical Research, 50 (4). pp. 1114-1123.

Dailler, David and Rocaboy, Ronan and Baudoin, Olivier. (2017) Synthesis of β-Lactams by Palladium(0)-Catalyzed C(sp3)−H Carbamoylation. Angewandte Chemie International Edition, 56 (25). pp. 7218-7222.

Holstein, Philipp M. and Holstein, Julian J. and Escudero-Adan, Eduardo C. and Baudoin, Olivier and Echavarren, Antonio M.. (2017) Ferrocene derivatives of liquid chiral molecules allow assignment of absolute configuration by X-ray crystallography. Tetrahedron: Asymmetry, 28 (10). pp. 1321-1329.

2016

Prieto, Alexis and Baudoin, Olivier and Bouyssi, Didier and Monteiro, Nuno. (2016) Electrophilic trifluoromethylation of carbonyl compounds and their nitrogen derivatives under copper catalysis. Chemical Communications, 52. pp. 869-881.

Holstein, Philipp M. and Dailler, David and Vantourout, Julien and Shaya, Janah and Millet, Anthony and Baudoin, Olivier. (2016) Synthesis of Strained γ-Lactams by Palladium(0)-Catalyzed C(sp3)−H Alkenylation and Application to Alkaloid Synthesis. Angewandte Chemie, 128 (8). pp. 2855-2859.

Martin, Anthony and Vors, Jean-Pierre and Baudoin, Olivier. (2016) Synthesis of Conformationally Constrained Esters and Amines by Pd-Catalyzed α-Arylation of Hindered Substrates. ACS Catalysis, 6 (6). pp. 3941-3945.

Dupuy, Stéphanie and Zhang, Ke-Feng and Goutierre, Anne-Sophie and Baudoin, Olivier. (2016) Terminal-Selective Functionalization of Alkyl Chains by Regioconvergent Cross-Coupling. Angewandte Chemie International Edition, 55 (47). pp. 14793-14797.

Baudoin, Olivier. (2016) Selectivity Control in the Palladium-catalyzed Cross-coupling of Alkyl Nucleophiles. Chimia, 70 (11). pp. 768-772.

Dailler, David and Danoun, Grégory and Baudoin, Olivier. (2016) Applications of Catalytic Organometallic C(sp3)–H Bond Functionalization. In: C-H bond activation and catalytic functionalization II. pp. 133-154.