Chapelat, Julien and Buss, Axel and Chougnet, Antoinette and Woggon, Wolf-D.. (2008) Diastereoselective synthesis of alpha -tocopherol : a new concept for the formation of chromanols. Organic letters, Vol. 10, H. 22. pp. 5123-5126.
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Official URL: http://edoc.unibas.ch/dok/A5260121
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Abstract
A diastereoselective synthesis of alpha-tocopherol (93% de) was achieved via two key steps, (i) a highly diastereoselective Shi epoxidn. of trisubstituted alkene I and (ii) an acid supported, "anti-Baldwin" epoxide ring opening under inversion of configuration leading to the 6-membered chromanol ring.
| Faculties and Departments: | 05 Faculty of Science 05 Faculty of Science > Departement Chemie > Chemie |
|---|---|
| UniBasel Contributors: | Woggon, Wolf-Dietrich |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | American Chemical Society |
| ISSN: | 1523-7060 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Last Modified: | 22 Mar 2012 14:24 |
| Deposited On: | 22 Mar 2012 13:43 |
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