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Alkylation of Ketones Catalyzed by Bifunctional Iron Complexes: From Mechanistic Understanding to Application

Seck, Charlotte and Mbaye, Diagne M. and Coufourier, Sébastien and Lator, Alexis and Lohier, Jean-François and Poater, Albert and Ward, Thomas R. and Gaillard, Sylvain and Renaud, Jean-Luc. (2017) Alkylation of Ketones Catalyzed by Bifunctional Iron Complexes: From Mechanistic Understanding to Application. ChemCatChem, 9 (23). pp. 4410-4416.

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Official URL: http://edoc.unibas.ch/58961/

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Abstract

Cyclopentadienone iron dicarbonyl complexes were applied in the alkylation of ketones with various aliphatic and aromatic ketones and alcohols via the borrowing hydrogen strategy in mild reaction conditions. DFT calculations and experimental works highlight the role of the transition metal Lewis pairs and the base. These iron complexes demonstrated a broad applicability in mild conditions and extended the scope of substrates.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Bioanorganische Chemie (Ward)
UniBasel Contributors:Ward, Thomas R. R.
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Wiley
ISSN:1867-3880
e-ISSN:1867-3899
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:22 Jan 2018 10:25
Deposited On:22 Jan 2018 10:25

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