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Functionalised 2,2 `-bipyridine ligands for the preparation of metallostars; X-ray structures of free ligands and preparation of copper(I) and silver(I) complexes

Constable, Edwin Charles and Housecroft, Catherine E. and Neuburger, Markus and Poleschak, Ingo and Zehnder, Margareta. (2003) Functionalised 2,2 `-bipyridine ligands for the preparation of metallostars; X-ray structures of free ligands and preparation of copper(I) and silver(I) complexes. Polyhedron, 22 (1). pp. 93-108.

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Abstract

2,2-Bipyridine ligands bearing functionalised aryl substituents have been prepared with the aim of subsequent functionalisation and the preparation of multinuclear metallostars. The key intermediates are compounds containing 4-methoxyphenyl substituents which may be converted to 4-hydroxyphenyl substituted ligands. Copper(I) and silver(I) complexes of 4,4`-di(methoxyphenyl)-6,6`-dimethyl-2,2`-bipyridine have been prepared and structurally characterised as have the ligands 4,4`-di(methoxypheny1)-6,6`-dimethyl-2,2`-bipyridine and 4,4`-di(methoxyphenyl)-2,2`-bipyridine.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
UniBasel Contributors:Constable, Edwin Charles
Item Type:Article, refereed
Publisher:Elsevier
ISSN:0277-5387
e-ISSN:1873-3719
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:12 Apr 2017 08:59
Deposited On:26 Apr 2016 13:50

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