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Electrochemical probing of ground state electronic interactions in polynuclear complexes of a new heteroditopic ligand

Constable, Edwin C. and Figgemeier, E. and Housecroft, Catherine E. and Olsson, J. and Zimmermann, Y. C.. (2004) Electrochemical probing of ground state electronic interactions in polynuclear complexes of a new heteroditopic ligand. Dalton Transactions, 13. pp. 1918-1927.

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Official URL: http://edoc.unibas.ch/39200/

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Abstract

The synthesis and electronic properties of dinuclear ([(bipy)(2)Ru(I)M(terpy)][PF6](4)(bipy = 2,2`-bipyridine, terpy = 2,2`: 6`, 2``-terpyridine; M = Ru, Os)) and trinuclear ([(bipy)(2)Ru(I)(2)M][PF6](6) M = Ru, Os, Fe, Co) complexes bridged by 4`-(2,2`-bipyridin-4-yl)-2,2`: 6`, 2``-terpyridine (I) have been investigated and are compared with those of mononuclear model complexes. The electrochemical analysis using cyclic voltammetry and differential pulse voltammetry reveals that there are no interactions in the ground state between adjacent metal centres. However, there is strong electronic communication between the 2,2`-bipyridine and 2,2`: 6``
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles
Item Type:Article, refereed
Publisher:Royal Society of Chemistry
ISSN:1477-9226
e-ISSN:1477-9234
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:12 Apr 2017 08:54
Deposited On:03 Feb 2016 09:32

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