Bünzli, Andreas. Color-tuning and stability enhancement of cyclometallated iridium (III) complexes in light-emitting electrochemical cells. 2015, PhD Thesis, University of Basel, Faculty of Science.
Available under License CC BY-NC-ND (Attribution-NonCommercial-NoDerivatives).
Official URL: http://edoc.unibas.ch/diss/DissB_11511
Chapter 1 highlights the historical progress of artificial light from the incandescent light bulb towards ultrathin highly-efficient flexible LEECs and their working principle.
Chapter 2 describes the synthesis and photophysical properties of orange-emitting Ir(III) complexes supported by theoretical calculations.
Chapter 3 addresses the synthesis and characterization of green-emitting Ir(III) complexes supported by theoretical calculations.
Chapter 4 reports the design of linking a blue-emitting naphthyl group to an orange-luminescent Ir(III) complex as well as mixing experiments of a blue and orange compound towards white-light emission.
Chapter 5 comprises the effect of multiple intra-cation π-stacking interactions on the long-term stability of Ir(III) complexes in LEECs.
Chapter 6 concludes the previous chapters and gives a short outlook for future work in the field of Ir(III) based LEECs.
|Advisors:||Constable, Edwin C.|
|Committee Members:||Wenger, Oliver S.|
|Faculties and Departments:||05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)|
|Bibsysno:||Link to catalogue|
|Number of Pages:||145 S.|
|Last Modified:||30 Jun 2016 10:58|
|Deposited On:||25 Nov 2015 15:31|
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