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[Fe(4′-PhStpy)2][PF6]2 (4′-PhStpy = 4′-phenylthio-2,2′:6′,2″-terpyridine) : a centrosymmetric embrace

Tao, Yaqiu and Constable, Edwin C. and Housecroft, Catherine E. and Neuburger, Markus. (2012) [Fe(4′-PhStpy)2][PF6]2 (4′-PhStpy = 4′-phenylthio-2,2′:6′,2″-terpyridine) : a centrosymmetric embrace. Inorganic Chemistry Communications, 20. pp. 180-183.

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Official URL: http://edoc.unibas.ch/dok/A6056188

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Abstract

The syntheses and characterizations of 4`-phenylthio-2,2`:6`,2 ``-terpyridine (4`-PhStpy) and [Fe(4`-PhStpy)(2)] [PF6](2) are reported. In the solid state, centrosymmetric pairs of [Fe(4`-PhStpy)(2)](2+) cations in [Fe(4`-Phstpy)(2)][PF6](2)center dot 2MeCN associate through face-to-face pi-stacking of pyridine rings, and twisting of the PhS substituents enables the cations to embrace one another, capturing four MeCN solvate molecules within the [Fe(4`-PhStpy)(2)](2)-motif.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles and Housecroft, Catherine Elizabeth and Neuburger, Markus
Item Type:Article, refereed
Publisher:Elsevier
ISSN:1387-7003
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:10 Apr 2017 14:15
Deposited On:01 Feb 2013 08:41

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