Constable, Edwin C. and Housecroft, Catherine E. and Medlycott, Elaine A. and Neuburger, Markus and Reinders, Federica and Reymann, Sebastien and Schaffner, Silvia. (2008) Bis(4′-phenyl-2,2′:6′,2″-terpyridine)ruthenium(II) : holding the {Ru(tpy)2}2+ embraces at bay. Inorganic Chemistry Communications, 11 (7). pp. 805-808.
Full text not available from this repository.
Official URL: http://edoc.unibas.ch/dok/A6056001
Downloads: Statistics Overview
Abstract
The solid state structure of [Ru(Phtpy)(2)][PF6](2)center dot 4MeCN has been determined (Phtpy = 4`-phenyl-2,2`:6`,2 ``-terpyridine); [Ru(Phtpy)(2)](2+) cations pack into sheets by virtue of M(tpy)(2)(2) embraces, and the MeCN solvent molecules are involved in N center dot center dot center dot H-C interactions which prevent the efficient packing of adjacent sheets. Comparisons with related structures lead to some generalizations about packing motifs in salts containing [M(Phtpy)(2)](2+) or [M(pytpy)(2)](2+) cations (pytpy = 4`-pyridyl-2,2`:6`,2 ``-terpyridine).
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Constable) |
|---|---|
| UniBasel Contributors: | Constable, Edwin Charles and Housecroft, Catherine Elizabeth and Neuburger, Markus |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Elsevier |
| ISSN: | 1387-7003 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: | |
| Last Modified: | 12 Apr 2017 06:51 |
| Deposited On: | 01 Feb 2013 08:40 |
Repository Staff Only: item control page