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Selective addressing of heteroditopic ligands by iron(II) and platinum(II)

Constable, Edwin C. and Housecroft, Catherine E. and Neuburger, Markus and Schaffner, Silvia and Shardlow, Ellen J.. (2007) Selective addressing of heteroditopic ligands by iron(II) and platinum(II). Inorganica Chimica Acta, 360 (15). pp. 4069-4076.

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Official URL: http://edoc.unibas.ch/dok/A6056007

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Abstract

The heteroditopic ligand 4`-(4,7,10-trioxadec-1-yn-10-yl)- 2,2`:6`,2 ``-terpyridine, 2, contains an N, N`, N ``-donor metal-binding domain that recognizes iron(II), and a terminal alkyne site that selectively couples to platinum( II). This selectivity has been used to investigate routes to the formation of heterometallic systems. The single crystal structures of ligand 2 and the complex [Fe(2)(2)][PF6](2) are reported.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles and Housecroft, Catherine Elizabeth and Neuburger, Markus
Item Type:Article, refereed
Publisher:Elsevier
ISSN:0020-1693
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:12 Apr 2017 07:35
Deposited On:01 Feb 2013 08:39

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