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Redox-Switching in a Viologen-type Adlayer : an Electrochemical Shell-Isolated Nanoparticle Enhanced Raman Spectroscopy Study on Au(111)-(1×1) Single Crystal Electrodes

Liu, Bo and Blaszczyk, Alfred and Mayor, Marcel and Wandlowski, Thomas. (2011) Redox-Switching in a Viologen-type Adlayer : an Electrochemical Shell-Isolated Nanoparticle Enhanced Raman Spectroscopy Study on Au(111)-(1×1) Single Crystal Electrodes. ACS Nano, 5 (7). pp. 5662-5672.

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Official URL: http://edoc.unibas.ch/dok/A5848538

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Abstract

We reported the first application of in situ shell-isolated nanoparticle enhanced Raman spectroscopy (SHINERS) to an interfacial redox reaction under electrochemical conditions. We construct gap-mode sandwich structures composed of a thiol-terminated HS-6V6H viologen adlayer immobilized on a single crystal Au(111)-(1×1) electrode and covered by Au(60 nm)@SiO2 core–shell nanoparticles acting as plasmonic antennas. We observed high-quality, potential-dependent Raman spectra of the three viologen species V2+, V+●, and V0 on a well-defined Au(111) substrate surface and could map their potential-dependent evolution. Comparison with experiments on powder samples revealed an enhancement factor of the nonresonant Raman modes of ∼3 × 105, and up to 9 × 107 for the resonance modes. The study illustrates the unique capability of SHINERS and its potential in the entire field of electrochemical surface science to explore structures and reaction pathways on well-defined substrate surfaces, such as single crystals, for molecular, (electro-)catalytic, bioelectrochemical systems up to fundamental double layer studies at electrified solid/liquid interfaces.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Molecular Devices and Materials (Mayor)
UniBasel Contributors:Mayor, Marcel
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:American Chemical Society
ISSN:1936-0851
e-ISSN:1936-086X
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:05 Apr 2017 12:47
Deposited On:14 Sep 2012 07:02

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