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Influence of the Anchor Group on Charge Transport through Single-Molecule Junctions

Lörtscher, Emanuel and Cho, Clara J. and Mayor, Marcel and Tschudy, Meinrad and Rettner, Charles and Riel, Heike. (2011) Influence of the Anchor Group on Charge Transport through Single-Molecule Junctions. ChemPhysChem, 12 (9). pp. 1677-1682.

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Official URL: http://edoc.unibas.ch/dok/A5843761

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Abstract

The molecule–metal coupling in molecular junctions is investigated at the single-molecule level by anchoring a phenyl ring, using either thiol (Figure, A) or isocyanide (Figure, B) linkers, to two gold electrodes of a mechanically controllable break-junction. The transport properties of the single-molecule junctions are recorded while repeatedly forming and breaking the molecular junction. Thiol linkage results in a 50 % larger molecular-level broadening compared to isocyano linkage.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Molecular Devices and Materials (Mayor)
UniBasel Contributors:Mayor, Marcel
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Wiley
ISSN:1439-4235
e-ISSN:1439-7641
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:05 Apr 2017 12:49
Deposited On:14 Sep 2012 07:01

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