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Disulfide struts : assembly motifs supporting a cuprocapsule

Constable, Edwin C. and Zhang, Guoqi and Housecroft, Catherine E. and Zampese, Jennifer A.. (2011) Disulfide struts : assembly motifs supporting a cuprocapsule. Inorganic Chemistry Communications, 14 (11). pp. 1703-1705.

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Official URL: http://edoc.unibas.ch/dok/A5848951

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Abstract

Condensation of 2-aminoethanethiol with 1,3-bis(3-formyl-2-hydroxyphenyl)-1,4,7,10,13-pentaoxatridecane in the presence of Cu(OAc)(2) and base is accompanied by oxidative coupling of pendant thiols with the formation of a disulfide-containing macrocycle H(2)1. This assembles the novel capsule [Cu-2(1)(2)] which hosts two CH2Cl2 guest molecules.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles and Housecroft, Catherine Elizabeth
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Elsevier
ISSN:1387-7003
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:10 Apr 2017 14:24
Deposited On:14 Sep 2012 07:01

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