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Supramolecular Cluster Catalysis: Benzene Hydrogenation Catalyzed by a Cationic Triruthenium Cluster under Biphasic Conditions

Suss-Fink, Georg and Faure, Matthieu and Ward, Thomas R.. (2002) Supramolecular Cluster Catalysis: Benzene Hydrogenation Catalyzed by a Cationic Triruthenium Cluster under Biphasic Conditions. Angewandte Chemie International Edition, 41 (1). pp. 99-101.

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Official URL: http://edoc.unibas.ch/dok/A5254480

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Abstract

At the interface of homogeneous, heterogeneous, and enzymatic catalysis is the catalytic hydrogenation of benzene to give cyclohexane by the triruthenium cluster 1. Experimental evidence and molecular modeling studies strongly support a catalytic mechanism in which the aromatic substrate is hydrogenated in the hydrophobic pocket spanned by the three η6-bound arene ligands without being coordinated to a Ru center.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Bioanorganische Chemie (Ward)
UniBasel Contributors:Ward, Thomas R. R.
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Wiley
ISSN:1433-7851
e-ISSN:1521-3773
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:24 Apr 2017 14:31
Deposited On:22 Mar 2012 14:07

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