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Preparation and photophysical studies of copper(I) and ruthenium(II) complexes of 4,4′-bis(3,5-dimethoxyphenyl)-6,6′-dimethyl-2,2′-bipyridine

Boudebous, Amar and Constable, Edwin C. and Housecroft, Catherine E. and Neuburger, Markus and Schaffner, Silvia and Listorti, Andrea and Sabatini, Cristiana and Barigelletti, Francesco. (2009) Preparation and photophysical studies of copper(I) and ruthenium(II) complexes of 4,4′-bis(3,5-dimethoxyphenyl)-6,6′-dimethyl-2,2′-bipyridine. Inorganica Chimica Acta, 362 (6). pp. 1825-1830.

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Official URL: http://edoc.unibas.ch/dok/A5251509

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Abstract

We report the synthesis of a new ligand, 4,4'-bis(3,5-dimethoxyphenyl)-6,6'-dimethyl-2,2'-bipyridine, optimised for binding to copper(I) and with pendant functionality that can eventually be developed into metallodendritic structures. The synthesis and photophysical properties of complexes with copper(I) and ruthenium(II) are reported. The solid state structure of the complex [Cu(1)(2)][PF6] center dot MeCN (1 = 4,4'-bis(3,5-dimethoxyphenyl)- 6,6'-dimethyl-2,2'-bipyridine) is also described. (C) 2008 Elsevier B. V. All rights reserved.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
UniBasel Contributors:Constable, Edwin Charles and Housecroft, Catherine Elizabeth and Neuburger, Markus
Item Type:Article, refereed
Publisher:Elsevier
ISSN:0020-1693
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:08 May 2017 08:49
Deposited On:22 Mar 2012 14:06

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