Surface plasmon enhanced photoconductance of gold nanoparticle arrays with incorporated alkane linkers

We report on a photoconductive gain effect in two-dimensional arrays of gold nanoparticles  NPs  in which alkane molecules are inserted. The NP arrays are formed by a self-assembly process from alkanethiol-coated gold NPs, and subsequently they are patterned on a Si/SiO2 chip by a microcontact printing technique. We find that the photoconductance of the arrays is strongly enhanced at the frequency of the surface plasmon of the NPs. We interpret the observation as a bolometric enhancement in the conductance of the NP arrays upon excitation of the surface plasmon resonance.